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Exclusive! Why Is Allylic Carbocation Stable

Allylic carbocations are a common conjugated system. This allows for overlap with double bonds.


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The positive charge of a carbocation is contained in a P orbital of a sp2 hybrizied carbon.

Why is allylic carbocation stable. Conjugation tends to stabilize molecules. The true structure of the conjugated allyl carbocation is a hybrid of of the two resonance structure so the positive charge is delocalized over the two terminal carbons. This delocalization stablizes the allyl carbocation making it more stable than a normal primary carbocation.

The resonance structures below help explain the stability of allylic carbocations. Allylic carbocations are a common conjugated system. The positive charge is more stable because it is spread over 2 carbons.


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